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  2. Redetermination of 1-carboxy-cyclo-hexan-1-aminium chloride

Redetermination of 1-carboxy-cyclo-hexan-1-aminium chloride Artículos académico

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Resumen

  • The crystal structure of the title compound, C7H14NO2 +· Cl-, was reported previously [Chacko, Srinivasan & Zand (1975). J. Cryst. Mol. Struct. 5, 353-357] from Weissenberg photographic data with R = 0.113. It has now been redetermined, providing a significant increase in the precision of the derived geometric parameters, viz. mean (C - C) = 0.003 Å in the present work compared with 0.021 Å for the previous work. The complete cation is generated by crystallographic mirrror symmetry, with three C atoms, two O atoms and the N atom lying on the reflecting plane; the chloride anion also has m site symmetry. The crystal structure is established by a two-dimensional network of O - H⋯Cl and N - H⋯Cl hydrogen bonds, generating C 1 2(4) and C 1 2(7) chains, and R 2 4(8) and R 2 4(14) rings.

Área temática

  • Fin de la pobreza

autores

  • http://research-hub.urosario.edu.co/ontology/vlocal#ExcludedPerson
    asiloe j mora
  • http://research-hub.urosario.edu.co/ontology/vlocal#ExcludedPerson
    gerzon e delgado
  • http://vivoweb.org/ontology/core#FacultyMember
    Luis Eduardo Seijas Ruiz
  • http://research-hub.urosario.edu.co/ontology/vlocal#ExcludedPerson
    lusbely m belandria
  • http://research-hub.urosario.edu.co/ontology/vlocal#ExcludedPerson
    teresa gonzalez

Edición

  • 65

fecha de publicación

  • 2009-1-1

Identidad

Identificador de objeto digital (DOI)

  • https://doi.org/10.1107/s1600536808044243

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