Fabricación y caracterización óptica de cristales coloidales de alta calidad formados por esferas de SiO2 de 225 nm de diámetro con empaquetamiento fcc crecidos por el método convectivo de auto-ensamblado de deposición vertical Academic Article

journal

  • Universitas Scientiarum

abstract

  • Objective: Fabrication and optical characterization of close-packed 225 nm SiO2 -based colloidal crystals. Materials and methods: The vertical convective self-assembly method is used to grow high-quality 225 nm close-packed SiO2-based colloidal crystals. An annealing process (550ampersand-flag-changedeg;C) is made in order to improve the mechanical stability of the sample. Optical characterization is done by angle-resolved transmission spectroscopy (A-RTS) and structural characterization by Scanning Electron Microscopy (SEM). Results: Both, A-RTS and SEM, show that with the vertical convective self-assembly method, with the appropriate parameters of temperature of evaporation (60ampersand-flag-changedeg;C), volume fraction of the colloidal suspension (0.2percent-flag-change w/w) and acidity (pH=6), highly ordered close packed face centered cubic (fcc) SiO2 based colloidal crystals are obtained. Conclusions: The growth of high-quality (long range order and defect-free) face centered cubic opalbased photonic crystals is reported.

publication date

  • 2010-4-1

edition

  • 15

keywords

  • acidity
  • annealing
  • characterization
  • colloids
  • crystals
  • defects
  • evaporation
  • fabrication
  • photonics
  • scanning electron microscopy
  • self assembly
  • spectroscopy
  • temperature

International Standard Serial Number (ISSN)

  • 0122-7483

number of pages

  • 9

start page

  • 150

end page

  • 158