Redetermination of 1-carboxy-cyclo-hexan-1-aminium chloride Academic Article

journal

  • Acta Crystallographica Section E: Structure Reports Online

abstract

  • The crystal structure of the title compound, C7H14NO2 ampersand-flag-changemiddot; Cl-, was reported previously [Chacko, Srinivasan y Zand (1975). J. Cryst. Mol. Struct. 5, 353-357] from Weissenberg photographic data with R = 0.113. It has now been redetermined, providing a significant increase in the precision of the derived geometric parameters, viz. mean (C - C) = 0.003 ampersand-flag-changeAring; in the present work compared with 0.021 ampersand-flag-changeAring; for the previous work. The complete cation is generated by crystallographic mirrror symmetry, with three C atoms, two O atoms and the N atom lying on the reflecting plane; the chloride anion also has m site symmetry. The crystal structure is established by a two-dimensional network of O - H⋯Cl and N - H⋯Cl hydrogen bonds, generating C 1 2(4) and C 1 2(7) chains, and R 2 4(8) and R 2 4(14) rings.

publication date

  • 2009-1-1

edition

  • 65

keywords

  • Anion
  • Atoms
  • Cation
  • Chloride
  • Crystal Structure
  • Crystal structure
  • Hydrogen Bond
  • Hydrogen bonds
  • Negative ions
  • Positive ions
  • X-Ray Weissenberg
  • anions
  • atoms
  • cations
  • chlorides
  • crystal structure
  • hydrogen bonds
  • rings
  • symmetry

International Standard Serial Number (ISSN)

  • 1600-5368

start page

  • o245